Structured silicalite-1 encapsulated Ni catalyst supported on SiC foam for dry reforming of methane

Structured silicalite-1 zeolite encapsulated Ni catalyst supported on silicon carbide foam (i.e., Ni@S1-SiC) was prepared using a new yet simple one-pot method, showing the significantly improved anti-sintering and anti-coking performance in comparison with the conventional supported and encapsulated Ni catalysts (i.e., Ni/S1, Ni/S1-SiC, and Ni@S1), in catalytic dry reforming of methane (DRM). The developed Ni-0.08@S1-SiC catalyst showed high CO2/CH4 conversions of >85% and H-2/CO molar ratio of >0.85 at 700 degrees C, outperforming other control catalysts under investigation. Additionally, the Ni-0.08@S1-SiC catalyst demonstrated high turnover frequency (TOF) values of similar to 5.6 and similar to 2.1/s regarding to CO2/CH4 conversions at 400 degrees C, exhibiting excellent stability and low pressure-drop during 100 hr on stream evaluation. Post-reaction characterization of the used catalysts demonstrated that the combination of zeolite encapsulated Ni catalysts and SiC foam enabled well-dispersed and ultrafine Ni nanoparticles, low pressure drop and intensified transfer steps, presented excellent anti-sintering and anti-coking abilities.