A correlation of electrochemical and spectroelectrochemical properties of poly(o-toluidine)

被引：32

作者：

Bilal, Salma ^{[2
]}

Shah, Anwar-ul-Haq Ali ^{[3
]}

Holze, Rudolf ^{[1
]}

机构：

[1] Tech Univ, Inst Chem, AG Elektrochem, D-09107 Chemnitz, Germany

[2] Kohat Univ Sci & Technol, Dept Chem, Kohat, Pakistan

[3] Univ Peshawar, Inst Chem Sci, Peshawar, Pakistan

来源：

ELECTROCHIMICA ACTA | 2009年 / 54卷 / 21期

关键词：

Poly(o-toluidine); Cyclic voltammetry; In situ conductivity; In situ UV-vis spectroelectrochemistry; Raman spectroelectrochemistry; 2 REDOX PROCESSES; CONDUCTING POLYMERS; CORROSION-PROTECTION; RAMAN-SPECTROSCOPY; SUBSTITUTED POLYANILINES; O-AMINOPHENOL; FILMS; POLY(O-PHENYLENEDIAMINE); COPOLYMERS; COATINGS;

D O I：

10.1016/j.electacta.2009.03.072

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A comparative discussion of the electrochemical and spectroelectrochemical properties of poly(o-toluidine) POT, a methyl substituted derivative of polyaniline, PANl, is presented. POT exists in various oxidation states and shows an insulator to conductor transition when doped by electrooxidation. The transformation of the polymer film from its non-concluding leucoemeraldine to its conducting emeraldine state and further on to its again non-conducting pernigraniline form was observed with different techniques including cyclic voltammetry, in situ conductivity measurements and in situ UV-vis and Raman spectroelectrochemical methods. Results reveal that POT shows a good correlation between its electrochemical and spectroelectrochemical properties in its different oxidation states. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：4851 / 4856

页数：6

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