Metallopolymers as an Emerging Class of Self-Healing Materials

被引：32

作者：

Sandmann, Benedict ^{[1
,2
]}

Bode, Stefan ^{[1
,2
]}

Hager, Martin D. ^{[1
,2
]}

Schubert, Ulrich S. ^{[1
,2
,3
]}

机构：

[1] Univ Jena, Lab Organ & Macromol Chem IOMC, D-07743 Jena, Germany

[2] Univ Jena, JCSM, D-07743 Jena, Germany

[3] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands

来源：

HIERARCHICAL MACROMOLECULAR STRUCTURES: 60 YEARS AFTER THE STAUDINGER NOBEL PRIZE II | 2013年 / 262卷

关键词：

Ionomers; Metallopolymers; Self-healing materials; Self-healing polymers; Supramolecular polymers; SUPRAMOLECULAR DIBLOCK COPOLYMER; CROSS-LINKING; MECHANICAL-PROPERTIES; MAGNETIC-PROPERTIES; POLYMERIC MATERIALS; MUSSEL BYSSUS; FIBERS DRAWN; SIDE-CHAINS; IONOMERS; COATINGS;

D O I：

10.1007/12_2013_242

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Metallopolymers are highly interesting materials with properties combining typical polymeric features with the properties of metal-ligand complexes. Thereby, the incorporation of different metal complexes into the polymeric material enables the tuning of the resulting material's properties. In particular, ionic interactions between charged metal complexes and the corresponding counterions as well as reversible (switchable) metal-ligand interactions make these materials potentially interesting as self-healing materials. Compared to other self-healing polymers, the research on these materials is still in its infancy. This review summarizes the latest trends in the research regarding this class of materials.

引用

页码：239 / 257

页数：19