A Chemical Approach to the Discovery of Quasicrystals and Their Approximant Crystals

被引：31

作者：

Lin, Qisheng

Corbett, John D. ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

CONTROLLED ASSEMBLY AND MODIFICATION OF INORGANIC SYSTEMS | 2009年 / 133卷

基金：

美国能源部; 美国国家科学基金会;

关键词：

Approximant crystals; Electronic tuning; Intermetallics; Pseudogap; Quasicrystals; 2/1 RATIONAL APPROXIMANT; HYPOELECTRONIC INDIUM; METALLIC PHASE; X-RAY; CLUSTERS; GALLIUM; SYSTEM; MG; ZN; AU;

D O I：

10.1007/430_2008_11

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review is intended to be a chemist-friendly introduction to what quasicrystals (QCs) and approximant crystals (ACs) are and what chemists may be able to contribute to the field. Readers will first be exposed to a must-know history of QC/ACs, then warmed up with the somewhat distant and prior concepts of metal clusters in halides, oxides etc., and then to polyanionic clusters in Zintl phases and intermetallic systems. Information on these last two has originated over about the last 50 years. We will draw on some more chemical insights and information on how these might be related and applicable to new and expanded QC and AC systems. Then follow our experiences on electronic and chemical tuning of five QC and AC systems and the structural regularities within ACs, from which important clues for quasicrystal structure modeling are evident.

引用

页码：1 / 39

页数：39

共 104 条

[21] Na(14)K(6)Tl(18)M (M=Mg, Zn, Cd, Hg) and Na13.5Sm0.5K6Tl18Na: Novel octahedral and centered icosahedral cluster phases related to the Mg2Zn11-type structure [J].

Dong, ZC ;

Corbett, JD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (09) :1006-1009

[22]

DONG ZC, 1995, J AM CHEM SOC, V37, P335

[23]

Dubois JM, 2005, USEFUL QUASICRYSTALS, P1, DOI 10.1142/9789812567888

[24] INDEXING PROBLEMS IN QUASICRYSTAL DIFFRACTION [J].

ELSER, V .

PHYSICAL REVIEW B, 1985, 32 (08) :4892-4898

[25] QUASI-CRYSTALS AND CRYSTALLINE APPROXIMANTS [J].

GOLDMAN, AI ;

KELTON, RF .

REVIEWS OF MODERN PHYSICS, 1993, 65 (01) :213-230

[26] Comparative structural study of the disordered MCd6 quasicrystal approximants -: art. no. 024203 [J].

Gómez, CP ;

Lidin, S .

PHYSICAL REVIEW B, 2003, 68 (02)

[27]

Gómez CP, 2001, ANGEW CHEM INT EDIT, V40, P4037, DOI 10.1002/1521-3773(20011105)40:21<4037::AID-ANIE4037>3.0.CO

[28]

2-9

[29]

HAHN T, 2002, INT TABLES CRYSTALLO, VA, P761

[30] Discussion on clusters, phasons and quasicrystal stabilisation [J].

Henley, CL ;

de Boissieu, M ;

Steurer, W .

PHILOSOPHICAL MAGAZINE, 2006, 86 (6-8) :1131-1151

← 1 2 3 4 5 6 7 8 9 10 →