Palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides by mixed acetic formic anhydride

被引：33

作者：

Berger, Philippe ^{[1
]}

Bessmernykh, Alla ^{[1
]}

Caille, Jean-Claude ^{[1
]}

Mignonac, Sylviane ^{[1
]}

机构：

[1] FINORGA SA, F-38670 Chasse Sur Rhone, France

来源：

SYNTHESIS-STUTTGART | 2006年 / 18期

关键词：

hydroxycarbonylation; palladium; catalysis; aryl bromides; carboxylic acids;

D O I：

10.1055/s-2006-950195

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides in the presence of acetic anhydride and lithium formate as a carbon monoxide source has been developed. The combination of palladium(II) acetate with 1,1'-bis(diphenylphosphino)ferrocene (dppf) is an efficient catalytic system when the reaction is carried out at 120 degrees C.

引用

页码：3106 / 3110

页数：5

共 22 条

[1]

BELLER M, 1996, APPL HOMOGENEOUS CAT, V1

[2] PALLADIUM-CATALYZED HYDROXYCARBONYLATION OF VINYL AND ARYL TRIFLATES - SYNTHESIS OF ALPHA,BETA-UNSATURATED AND AROMATIC CARBOXYLIC-ACIDS [J].