Measurement of flooding in gas diffusion layers of polymer electrolyte fuel cells with conventional flow field

被引:52
作者
Yamada, Haruhiko [1 ]
Hatanaka, Tatsuya [1 ]
Murata, Hajime [1 ]
Morimoto, Yu [1 ]
机构
[1] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan
关键词
D O I
10.1149/1.2218812
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The objective of this work is to clarify the location and magnitude of flooding in polymer electrolyte fuel cells with a conventional flow field experimentally and by a numerical calculation. In the experiment, a newly developed cell with a conventional, interdigitated-switchable gas-flow field was used and the pressure drop between the inlet and outlet of the cathode was measured with the interdigitated flow field after the cell was operated with the conventional flow field. Significant pressure drop was observed after high current densities were flown; the pressure drop indicates the flooding level in a gas diffusion layer (GDL) during the conventional flow field operation. The cell performance and the flooding behavior depended significantly on wetting properties of catalyst layers and GDLs. In the simulation, liquid water distribution in the cathode GDL was predicted using a two-phase model, and validated by comparing the pressure drop measured and calculated using a gas-flow model. The simulation results agreed well with experimental data at high humidity condition and showed that a large amount of liquid water exists in the cathode GDL at high current densities.
引用
收藏
页码:A1748 / A1754
页数:7
相关论文
共 16 条
[1]   Relationship between pressure drop and cell resistance as a diagnostic tool for PEM fuel cells [J].
Barbir, F ;
Gorgun, H ;
Wang, X .
JOURNAL OF POWER SOURCES, 2005, 141 (01) :96-101
[2]   A 3D, multiphase, multicomponent model of the cathode and anode of a PEM fuel cell [J].
Berning, T ;
Djilali, N .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) :A1589-A1598
[3]  
CHUANG PA, 2005, 207 EL SOC M QUEB CI
[4]   Diagnostic tool to detect electrode flooding in proton-exchange-membrane fuel cells [J].
He, WS ;
Lin, GY ;
Nguyen, TV .
AICHE JOURNAL, 2003, 49 (12) :3221-3228
[5]   Two-phase flow model of the cathode of PEM fuel cells using interdigitated flow fields [J].
He, WS ;
Yi, JS ;
Nguyen, TV .
AICHE JOURNAL, 2000, 46 (10) :2053-2064
[6]   Rigorous 3-d mathematical modeling of PEM fuel cells - II. Model predictions with liquid water transport [J].
Mazumder, S ;
Cole, JV .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (11) :A1510-A1517
[7]   A two-dimensional, two-phase, multicomponent, transient model for the cathode of a proton exchange membrane fuel cell using conventional gas distributors [J].
Natarajan, D ;
Nguyen, TV .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (12) :A1324-A1335
[8]   Liquid water transport in gas diffusion layer of polymer electrolyte fuel cells [J].
Pasaogullari, U ;
Wang, CY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (03) :A399-A406
[9]   In situ neutron imaging technique for evaluation of water management systems in operating PEM fuel cells [J].
Satija, R ;
Jacobson, DL ;
Arif, M ;
Werner, SA .
JOURNAL OF POWER SOURCES, 2004, 129 (02) :238-245
[10]   Visualization of water buildup in the cathode of a transparent PEM fuel cell [J].
Tüber, K ;
Pócza, D ;
Hebling, C .
JOURNAL OF POWER SOURCES, 2003, 124 (02) :403-414