Concepts of ionic solvation

被引:0
作者
Krienke, H [1 ]
机构
[1] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany
来源
NOVEL APPROACHES TO THE STRUCTURE AND DYNAMICS OF LIQUIDS: EXPERIMENTS, THEORIES AND SIMULATIONS | 2004年
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The general features of ion solvation, of the solvent structure around solutes, and their influence on solution properties, are discussed in the framework of simple theoretical approaches, starting from classical molecular models. Ionic solvation is studied with integral equation methods. Analytical solutions for pair correlations and thermodynamics are discussed for the case of solution of charged hard spheres in polarizable dipolar hard spheres in the framework of the MSA and LIN approximations.
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页码:93 / 110
页数:18
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