First planar chiral bidentate ligand based on a (η5-cyclopentadienyl)(η4-cyclobutadiene) cobalt backbone:: high efficiency in enantioselective palladium-catalyzed allylic substitutions

被引：23

作者：

Arrayás, RG ^{[1
]}

Mancheño, OG ^{[1
]}

Carretero, JC ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ, E-28049 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 14期

关键词：

D O I：

10.1039/b405342g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of the planar chiral (R)-[eta(5)-(1-diphenylphosphino-2- tert-butylsulfenyl) cyclopentadienyl](eta(4)-tetraphenylcyclobutadiene) cobalt and its high efficiency as P, S-bidentate ligand in Pd-catalyzed allylic substitutions is described.

引用

页码：1654 / 1655

页数：2

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