Syntheses and characterizations of zinc(II) compounds containing three-dimensional interpenetrating diamondoid networks constructed by mixed ligands

被引：201

作者：

Li, XJ ^{[1
]}

Cao, R ^{[1
]}

Sun, DF ^{[1
]}

Bi, WH ^{[1
]}

Wang, YQ ^{[1
]}

Li, X ^{[1
]}

Hong, MC ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2004年 / 4卷 / 04期

关键词：

D O I：

10.1021/cg049949d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three three-dimensional interpenetrating diamondoid zinc(II) compounds, [Zn(bpe)(OH-BDC)](n) (1), {[Zn(dpe)(OH-BDC)](dpe)(0.5)}(n) (2), and J[Zn(bpp)(OH-BDC)](H2O)}(n) (3), have been prepared solvothermally by assembly of OH-H2BDC, Zn-II with bpe, dpe, and bpp, respectively [OH-H2BDC = 5-hydroxyisophthalic acid, bpe = 1,2-bis(4-pyridyl)ethane, dpe = 1,2-di(4-pyridyl)ethylene, and bpp = 1,3-bi(4-pyridyl)propanel. Single-crystal X-ray diffraction analyses reveal that 1 is a 5-fold interpenetrating diamondoid network, and 2 and 3 are 4-fold interpenetrating diamondoid structures with dpe guest molecules and water molecules, respectively.

引用

页码：775 / 780

页数：6

共 69 条

[1] Hydroxylated nanoballs: synthesis, crystal structure, solubility and crystallization on surfaces [J].