Effect of strontia on the densification and mechanical properties of sol-gel alumina

Boehmite sol was prepared by hot water hydrolysis of aluminum iso-propoxide using nitric acid as the catalyst. Hydrolysis was carried out at 80 degrees C for 80 min. Calcium nitrate was added and the peptization was complete at 80 degrees C for I h. The sol was precipitated in ammonia, the precipitate was aged for 24 h, dried at 120 degrees C and calcined at 500 degrees C for 3 h. The calcined powder was milled at 230 rpm for 6 h. The amount of calcium oxide was varied from I to 20 vol.%. The particle size and particle size distribution of the calcined powders were studied. The average particle size was found to increase with calcia content. The powder was compacted into cylindrical pellets using uni-axial press at 180 MPa and sintered at 1600 degrees C for 6 h. Mechanical properties such as hardness, fracture toughness, diametrical tensile strength and flexural strength for compacts containing various concentrations of strontium oxide was studied. There was a slight decrease in the density with increase in strontia content. Increase in the mechanical properties such as hardness, fracture toughness and diametrical tensile strength was observed with increase in strontia content. (C) 2005 Elsevier Ltd and Techna Group S.r.l. All rights reserved.