Branched trichain sulfosuccinates as novel water in CO2 dispersants

被引：44
作者：
Gold, Sarah
Eastoe, Julian [1 ]
Grilli, Roberto
Steytler, David C.
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ E Anglia, Sch Chem Sci & Pharm, Norwich NR4 7TJ, Norfolk, England
来源：
COLLOID AND POLYMER SCIENCE | 2006年 / 284卷 / 11期
关键词：
CO2; active surfactants; tri-chain surfactants; near infrared spectroscopy;
D O I：
10.1007/s00396-006-1519-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of highly branched trichain sulfosuccinate surfactants have been synthesized and studied in condensed CO2 and aqueous environments. Aqueous critical micelle concentrations (CMCs) showed a general trend of increasing CMC with decreasing chain length, whereas increased branching appeared to increase solubility in CO2 and aid the dispersion of water. Near infrared spectra confirmed observed cloud with a large increase in solubility above the cloud pressures in this solvent.
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收藏
页码：1333 / 1337
页数：5
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