Experimental Measurement and Modeling of Solubility Data for 2,3-Dichloronitrobenzene in Methanol, Ethanol, and Liquid Mixtures (Methanol plus Water, Ethanol plus Water)

被引：18

作者：

Li, Rongrong ^{[1
]}

Zhang, Bin ^{[2
]}

Wang, Ling ^{[3
]}

Yao, Ganbing ^{[3
]}

Zhang, Yingjie ^{[1
]}

Zhao, Hongkun ^{[3
]}

机构：

[1] TaiZhou Univ, Inst Appl Chem, Linhai 317000, Zhejiang, Peoples R China

[2] Ctr Coordinat & Support SAS TIND, Beijing 100191, Peoples R China

[3] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2014年 / 59卷 / 11期

关键词：

SOLVENT MIXTURES; ORGANIC-SOLVENTS; ACID;

D O I：

10.1021/je500494d

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubilities of 2,3-dichloronitrobenzene in aqueous solutions of methanol and ethanol with various concentrations were determined at temperatures ranging from (278.15 to 303.15) K under atmospheric pressure of 0.1 MPa. The solubility of 2,3-dichloronitrobenzene increases with increments in both temperature and mass fraction of methanol or ethanol. The solubility data were correlated by five models, which are the JouybanAcree model, van't HoffAcree model, modified ApelblatAcree model, Ma model, and Sun model. The calculated solubility using the JouybanAcree model shows better agreement with the experimental data than those by the other models. The thermodynamic properties, molar dissolution enthalpy, molar dissolution entropy, and Gibbs free energy change of dissolution process of 2,3-dichloronitrobenzene in two mixed solvents were calculated.

引用

页码：3586 / 3592

页数：7

共 50 条

[31] Sucrose Solubility in Binary Liquid Mixtures Formed by Water-Methanol, Water-Ethanol, and Methanol-Ethanol at 303 and 313 K
Galvao, Alessandro C.
Robazza, Weber S.
Sarturi, Geiza N.
Goulart, Fernanda C.
Conte, Daiane
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (09): : 2997 - 3002
[32] Measurement and calculation of solid-liquid equilibrium for ternary systems of 3,4-dichloronitrobenzene+2,3-dichloronitrobenzene plus ethanol/n-propanol
Li, Rongrong
Han, Shuo
Du, Cunbin
Meng, Long
Wang, Jian
Zhao, Hongkun
JOURNAL OF CHEMICAL THERMODYNAMICS, 2016, 98 : 140 - 148
[33] Rapid spectroscopic measurement of methanol in water-ethanol-methanol mixtures
Vaskova, Hana
Tomecek, Martin
22ND INTERNATIONAL CONFERENCE ON CIRCUITS, SYSTEMS, COMMUNICATIONS AND COMPUTERS (CSCC 2018), 2018, 210
[34] Solubility of DL-malic acid in water, ethanol and in mixtures of ethanol plus water
Yuan, Ye
Leng, Yixin
Shao, Hui
Huang, Chunxiang
Shan, Kai
FLUID PHASE EQUILIBRIA, 2014, 377 : 27 - 32
[35] SOLUBILITY OF HELIUM IN METHANOL PLUS WATER, ETHANOL PLUS WATER, 1-PROPANOL PLUS WATER, AND 2-PROPANOL PLUS WATER SOLUTIONS AT 25-DEGREES-C
YAMAMOTO, H
ICHIKAWA, K
TOKUNAGA, J
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (01): : 155 - 157
[36] Modeling and experimental measurement of NaBr solubility in water, methanol, ethanol, 1-propanol, and its mixtures at different temperatures
Ferrari, Ana C. G.
Corazza, Marcos L.
Voll, Fernando A. P.
DIGITAL CHEMICAL ENGINEERING, 2023, 6
[37] Conductometric studies on solvation behaviour of citric acid in water plus methanol and water plus ethanol mixtures at different temperatures
Bhat, J. Ishwara
Manjunatha, M. N.
INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 2010, 17 (06) : 462 - 467
[38] Solution thermodynamics of trans-Cinnamic acid in (methanol plus water) and (ethanol plus water) mixtures at different temperatures
Noubigh, Adel
Akremi, Ali
JOURNAL OF MOLECULAR LIQUIDS, 2019, 274 : 752 - 758
[39] The solubility of thiourea in water, methanol, and ethanol
Shnidman, L
JOURNAL OF PHYSICAL CHEMISTRY, 1933, 37 (06): : 693 - 700
[40] LLE DATA FOR THE SYSTEMS WATER PLUS (METHANOL OR ETHANOL) PLUS N-AMYL ACETATE
ARCE, A
BLANCO, A
MARTINEZAGEITOS, J
VIDAL, I
FLUID PHASE EQUILIBRIA, 1995, 109 (02) : 291 - 297

← 1 2 3 4 5 →