Esterification of Organic Acid in Bio-Oil using Acidic Ionic Liquid Catalysts

被引：76

作者：

Xiong, Wan-Ming ^{[1
]}

Zhu, Man-Zhou ^{[1
]}

Deng, Li ^{[1
]}

Fu, Yao ^{[1
]}

Guo, Qing-Xiang ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

来源：

ENERGY & FUELS | 2009年 / 23卷 / 3-4期

关键词：

FAST PYROLYSIS; MODEL COMPOUNDS; ACETIC-ACID; BIOMASS; CONVERSION; HYDROGEN; DESIGN; SYSTEM; ESTERS; FUELS;

D O I：

10.1021/ef801021j

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A dicationic ionic liquid C-6(mim)(2)-HSO4 was synthesized and used as the catalyst for bio-oil upgrading through the esterificartion reaction of organic acids and ethanol at room temperature. The reaction system turned into two layers when the reaction was complete. No coke and deactivation on the catalyst were observed. The yield of upgraded oil was about 49%, and its properties were significantly improved. The higher heating value approached to 24.6 MJ/kg, the pH value increased from 2.9 to 5.1, and the moisture decreased from 29.8 to 8.2 wt %. The chemical composition of the upgraded bio-oil was analyzed with GC-MS. The results showed that organic acids were successfully converted into esters. Thus our data indicated that the dicationic ionic liquid was a promising catalyst for esterification to upgrade bio-oil.

引用

页码：2278 / 2283

页数：6

共 38 条

[1] PRODUCTION OF HYDROCARBONS BY CATALYTIC UPGRADING OF A FAST PYROLYSIS BIO-OIL .1. CONVERSION OVER VARIOUS CATALYSTS [J].

ADJAYE, JD ;

BAKHSHI, NN .

FUEL PROCESSING TECHNOLOGY, 1995, 45 (03) :161-183

[2] Structure and properties of high stability geminal dicationic ionic liquids [J].

Anderson, JL ;

Ding, RF ;

Ellern, A ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (02) :593-604

[3] Ionic liquid structure effect upon reactivity of toluene carbonylation: 1. Organic cation structure [J].

Angueira, EJ ;

White, MG .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 238 (1-2) :163-174

[4] Novel bronsted acidic ionic liquids and their use as dual solvent-catalysts [J].

Cole, AC ;

Jensen, JL ;

Ntai, I ;

Tran, KLT ;

Weaver, KJ ;

Forbes, DC ;

Davis, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5962-5963

[5] Investigations into the control of odour and viscosity of biomass oil derived from pyrolysis of sewage sludge [J].

Doshi, VA ;

Vuthaluru, HB ;

Bastow, T .

FUEL PROCESSING TECHNOLOGY, 2005, 86 (08) :885-897

[6] DEVELOPMENTS IN DIRECT THERMOCHEMICAL LIQUEFACTION OF BIOMASS - 1983-1990 [J].

ELLIOTT, DC ;

BECKMAN, D ;

BRIDGWATER, AV ;

DIEBOLD, JP ;

GEVERT, SB ;

SOLANTAUSTA, Y .

ENERGY & FUELS, 1991, 5 (03) :399-410

[7] From dysfunction to bis-function: On the design and applications of functionalised ionic liquids [J].

Fei, ZF ;

Geldbach, TJ ;

Zhao, DB ;

Dyson, PJ .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (08) :2122-2130

[8] Hydrogen production by steam reforming of bio-oil using coprecipitated Ni-Al catalysts.: Acetic acid as a model compound [J].

Galdámez, JR ;

García, L ;

Bilbao, R .

ENERGY & FUELS, 2005, 19 (03) :1133-1142

[9] Bronsted acidic ionic liquids derived from alkylamines as catalysts and mediums for Fischer esterification: Study of structure-activity relationship [J].

Ganeshpure, Pralhad A. ;

George, Gigi ;

Das, Jagannath .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 279 (02) :182-186

[10] Acidic ionic liquid [bmim]HSO4:: An efficient catalyst for acetalization and thioacetalization of carbonyl compounds and their subsequent deprotection [J].

Gupta, Neeraj ;

Sonu ;

Kad, Goverdhan L. ;

Singh, Jasvinder .

CATALYSIS COMMUNICATIONS, 2007, 8 (09) :1323-1328

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