Influence of the composition on the copper diffusion in copper sulfides - Study by impedance spectroscopy

被引：15

作者：

Cassaignon, S

Sanchez, S

Guillemoles, JF

Vedel, J

Meier, HG

机构：

[1] ENSCP, Lab Electrochim & Chim Analyt, UMR 7575, F-75231 Paris 05, France

[2] Pontificia Univ Catolica Valparaiso, Fac Ciencias Basicas & Matemat, Inst Quim, Lab Electrochim, Valparaiso, Chile

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1999年 / 146卷 / 12期

关键词：

D O I：

10.1149/1.1392691

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Diffusion of copper in copper sulfides, Cu2-xS is studied as a function of x by means of electrochemical impedance spectroscopy (EIS) at room temperature. Copper sulfide compositions were determined from electromotive force determinations in the Cu\Cu(2+)aq\Cu2-xS galvanic cell. The same cell was used to change the x value by imposing a potential different of the equilibrium one. Experimental EIS determinations relate diffusion coefficients and concentrations of diffusing species. The experimental data are discussed accordingly. (C) 1939 The Electrochemical Society. S0013-4651(99)01-087-3. All rights reserved.

引用

页码：4666 / 4671

页数：6

共 21 条

[1] COPPER ELECTROMIGRATION IN POLYCRYSTALLINE COPPER SULFIDE [J].

ALLEN, LH ;

BUHKS, E .

JOURNAL OF APPLIED PHYSICS, 1984, 56 (02) :327-335

[2] Copper Diffusion in Copper Sulfide: a Systematic Study [J].

Cassaignon, S. ;

Pauporte, Th. ;

Guillemoles, J. -F. ;

Vedel, J. .

IONICS, 1998, 4 (5-6) :364-371

[3]

CASTEL E, 1977, THESIS P M CURIE PAR

[4] AN X-RAY STUDY ON THE SYSTEM CU-S [J].

DJURLE, S .

ACTA CHEMICA SCANDINAVICA, 1958, 12 (07) :1415-1426

[5] CRYSTAL STRUCTURE OF LOW CHALCOCITE [J].

EVANS, HT .

NATURE-PHYSICAL SCIENCE, 1971, 232 (29) :69-&

[6] EXPERIMENTAL AND THEORETICAL INVESTIGATION OF THE CRYSTAL-STRUCTURE OF CUS [J].

GOTSIS, HJ ;

BARNES, AC ;

STRANGE, P .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1992, 4 (50) :10461-10468

[7] CRYSTAL STRUCTURE OF ANILITE [J].

KOTO, K ;

MORIMOT, N .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 :915-&

[8] ELECTROCHEMICAL AND THERMODYNAMIC STUDIES ON SYSTEM COPPER-SULFUR AT TEMPERATURES T-15-90 DEGREES C [J].

MATHIEU, HJ ;

RICKERT, H .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1972, 79 (5-6) :315-&

[9]

Morimoto N., 1962, MINERAL J, V3, P338, DOI [10.2465/minerj1953.3.338, DOI 10.2465/MINERJ1953.3.338]

[10]

NEUILLY S, 1993, MODELISATION ESTIMAT

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