Silver(I) and Copper(I) Cocatalyzed Tandem Reaction of 2-Alkynylbenzaldoximes with Aldehydes or Alcohols: Approach to 4-Carboxylated Isoquinolines

被引：9

作者：

Wang, Xianbo ^{[1
]}

Yu, Xingxin ^{[2
]}

机构：

[1] Nanchang Univ, Dept Chem, Nanchang 330031, Jiangxi, Peoples R China

[2] E China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab New Drug Design, Shanghai 200237, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 17期

关键词：

TRIFLATE-CATALYZED REACTION; DIVERSITY; ESTERIFICATION; OXIDATION;

D O I：

10.1021/jo500864b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and efficient route for the preparation of 4-carboxylated isoquinolines via a Ag(I) and Cu(I) cocatalyzed tandem reaction of 2-alkynylbenzaldoximes with aldehydes or alcohols in moderate to good yields is described. The reaction proceeds smoothly to produce C-N and C-O bonds in a one-pot procedure with structural complexity and molecular diversity.

引用

页码：7854 / 7860

页数：7

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