Linearly conjugated benzocyclohexadienone photochemistry in the solid state: ionic chiral auxiliary mediated asymmetric induction

被引：18

作者：

Cheung, E ^{[1
]}

Netherton, MR ^{[1
]}

Scheffer, JR ^{[1
]}

Trotter, J ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 50期

关键词：

asymmetric induction; ketones; photochemistry; pi(a)(2)+sigma(a)(2)] rearrangement;

D O I：

10.1016/S0040-4039(99)01868-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric induction in the photochemistry of a linearly conjugated benzocyclohexadienone derivative has been achieved for the first time through the use of the solid state ionic chiral auxiliary method. Enantiomeric excesses as high as 70-80% at reasonable conversions are readily attainable. Crystal structures for both reactant and product are reported. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：8737 / 8740

页数：4