Synthesis of 6-aminophenanthridines via palladium-catalyzed insertion of isocyanides into N-sulfonyl-2-aminobiaryls

被引：30
作者：
Jiang, Huanfeng [1 ]
Gao, Hanling [1 ]
Liu, Bifu [1 ]
Wu, Wanqing [1 ]
机构：
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou, Guangdong, Peoples R China
来源：
RSC ADVANCES | 2014年 / 4卷 / 33期
基金：
中国国家自然科学基金;
关键词：
PD-C BOND; PHENANTHRIDINE DERIVATIVES; OXIDATIVE CYCLIZATION; 3-COMPONENT REACTION; ORTHO-PALLADATION; MULTICOMPONENT REACTIONS; EFFICIENT SYNTHESIS; CARBON-MONOXIDE; METHYL-ESTER; ARYL HALIDES;
D O I：
10.1039/c4ra02381a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A robust route to a diverse set of 6-aminophenanthridines via palladium-catalyzed C-H activation of N-sulfonyl-2-aminobiaryl and iso-cyanide insertion is reported. This transformation could also provide an important approach for building core frameworks of conjugated organic polymer materials.
引用
收藏
页码：17222 / 17225
页数：4
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