Theoretical model for the anodic oxidation of organics on metal oxide electrodes

被引：275

作者：

Simond, O ^{[1
]}

Schaller, V ^{[1
]}

Comninellis, C ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,INST CHEM ENGN,CH-1015 LAUSANNE,SWITZERLAND

来源：

ELECTROCHIMICA ACTA | 1997年 / 42卷 / 13-14期

关键词：

redox catalysis; anodic organics oxidation; metal oxide anode; indirect oxidation; oxygen evolution;

D O I：

10.1016/S0013-4686(97)85475-8

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A theoretical model describing the electrochemical oxidation of organics at oxide electrodes (MOx) forming the higher oxide (MOx+1) is described. In this model both organics oxidation and O-2 evolution are mediated by the higher oxide (MOx+1) which is electrogenerated at the anode surface. The effect of concentration polarization in the electrolyte is also included in the theoretical model. (C) 1997 Elsevier Science Ltd.

引用

页码：2009 / 2012

页数：4

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