CIGSS films prepared by sol-gel route

被引:45
作者
Oliveira, L. [1 ]
Todorov, T. [1 ]
Chassaing, E. [2 ]
LinCot, D. [2 ]
Carda, J. [1 ]
Escribano, P. [1 ]
机构
[1] Univ Jaume 1, Organ & Inorgan Chem Dept, Castellon De La Plana 12071, Spain
[2] IRDEP, F-78401 Chatou, France
关键词
Chalcopyrite; Spin-coating; Pentanary; Sol-gel; Photovoltaic; Low-cost; Band gap; CUINS2; FILMS; CELLS; ELECTRODEPOSITION; DEPOSITION; PRESSURE; MODULES;
D O I
10.1016/j.tsf.2008.10.104
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Homogeneous layers of amorphous oxides of Cu-In, Cu-In-Ga were deposited by a sol-gel method. Selenization, sulfurization and sequential selenization + sulfurization treatments were performed with elemental S and Se, respectively. Adherent pinhole-free layers were observed by scanning electron microscopy. X-ray diffraction indicated increased gallium incorporation in selenized in comparison with sulfurized films. Band gap values in the range of 1.18-1.63 eV were obtained. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:2272 / 2276
页数:5
相关论文
共 17 条
[1]   Synthesis of homogeneous pentenary chalcopyrite alloys with a classical two-step growth process [J].
Dhlamini, FD ;
Alberts, V .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2005, 66 (11) :1880-1882
[2]   Five-source PVD for the deposition of Cu(In1-xGax)(Se1-ySy)2 absorber layers [J].
Gossla, M ;
Shafarman, WN .
THIN SOLID FILMS, 2005, 480 :33-36
[3]   One, step electrodeposition of CuInSe2: Improved structural, electronic, and photovoltaic properties by annealing under high selenium pressure [J].
Guillemoles, JF ;
Cowache, P ;
Lusson, A ;
Fezzaa, K ;
Boisivon, F ;
Vedel, J ;
Lincot, D .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (09) :7293-7302
[4]  
Jensen Cynthia L., 1993, P 23 IEEE PHOT SPEC, P577
[5]   Low cost processing of CIGS thin film solar cells [J].
Kaelin, M ;
Rudmann, D ;
Tiwari, AN .
SOLAR ENERGY, 2004, 77 (06) :749-756
[6]   Improved performance of thin film solar cells based on Cu(In,Ga)S2 [J].
Kaigawa, R ;
Neisser, A ;
Klenk, R ;
Lux-Steiner, MC .
THIN SOLID FILMS, 2002, 415 (1-2) :266-271
[7]   Non-vacuum processing of CuIn1-xGaxSe2 solar cells on rigid and flexible substrates using nanoparticle precursor inks [J].
Kapur, VK ;
Bansal, A ;
Le, P ;
Asensio, OI .
THIN SOLID FILMS, 2003, 431 :53-57
[8]   Solar cells based on CuInS2 -: an overview [J].
Klenk, R ;
Klaer, J ;
Scheer, R ;
Lux-Steiner, MC ;
Luck, I ;
Meyer, N ;
Rühle, U .
THIN SOLID FILMS, 2005, 480 :509-514
[9]   In-line deposited Cu(In,Ga)Se2 solar cells:: influence of deposition temperature and Na co-evaporation on carrier collection [J].
Lammer, M ;
Kniese, R ;
Powalla, M .
THIN SOLID FILMS, 2004, 451 :175-178
[10]   Effect of Ga incorporation in sequentially prepared CuInS2 thin film absorbers [J].
Neisser, A ;
Hengel, I ;
Klenk, R ;
Matthes, TW ;
Alvarez-García, J ;
Pérez-Rodríguez, A ;
Romano-Rodríguez, A ;
Lux-Steiner, MC .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 67 (1-4) :97-104