A double hetero[4]helicene composed of two phenothiazines: synthesis, structural properties, and cationic states

被引：51

作者：

Sakamaki, Daisuke ^{[1
]}

Kumano, Daisuke ^{[2
]}

Yashima, Eiji ^{[2
]}

Seki, Shu ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Kyoto 6158510, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Nagoya, Aichi 4648603, Japan

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 97期

基金：

日本学术振兴会;

关键词：

PHOTOINDUCED ELECTRON-TRANSFER; DOUBLE HELICENE; RADICAL-CATION; PI-SYSTEMS; HETEROHELICENES; RESOLUTION; MOLECULES; THIOPHENE; DICATIONS; EXCHANGE;

D O I：

10.1039/c5cc07680c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel double hetero[4]helicene consisting of two phenothiazines (1) has been synthesized. The racemization barrier of 1 is high enough for optical separation. We successfully obtained the single crystals of the radical cation salt of 1 center dot(+), whose torsion angles were decreased compared to those of the neutral state.

引用

页码：17237 / 17240

页数：4

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