Vertically Ordered Hematite Nanotube Array as an Ultrasensitive and Rapid Response Acetone Sensor

被引:82
作者
Kim, Do Hong [1 ,2 ]
Shim, Young-Seok [1 ]
Jeon, Jong-Myeong [1 ]
Jeon, Hu Young [3 ]
Park, Sung Soo [4 ]
Kim, Young-Woon [1 ]
Rim, Jin-Sang [5 ]
Lee, Jong-Heun [2 ]
Jang, Ho Won [1 ]
机构
[1] Seoul Natl Univ, Res Inst Adv Mat, Dept Mat Sci Engn, Seoul 151744, South Korea
[2] Korea Univ, Dept Mat Sci Engn, Seoul 136713, South Korea
[3] Ulsan Natl Inst Sci & Technol, UCRF, Ulsan 689798, South Korea
[4] Ulsan Natl Inst Sci & Technol, Sch Mat Sci & Engn, Ulsan 689798, South Korea
[5] Korea Inst Sci & Technol, Elect Mat Res Ctr, Seoul 136791, South Korea
基金
新加坡国家研究基金会;
关键词
hematite; nanotube array; acetone sensor; earth abundant; ultrasensitive; GAS-SENSING PROPERTIES; HYDROTHERMAL SYNTHESIS; GROWTH-MECHANISM; ALPHA-FE2O3; TRANSPARENT; PERFORMANCE;
D O I
10.1021/am504156w
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Vertically ordered nanotube array is a desirable configuration to improve gas sensing properties of the hematite which is the most abundant and cheapest metal oxide semiconductor on earth but has low and sluggish chemiresistive responses. We have synthesized a vertically aligned, highly ordered hematite nanotube array directly on a patterned SiO2/Si substrate and then it used as a gas sensor without additional processing. The nanotube array sensor shows unprecedentedly ultrahigh and selective responses to acetone with detection limits down to a few parts per billion and response time shorter than 3 s.
引用
收藏
页码:14779 / 14784
页数:6
相关论文
共 32 条
[1]   Properties of the Nanoporous Anodic Oxide Electrochemically Grown on Steel in Hot 50% NaOH [J].
Burleigh, T. D. ;
Schmuki, P. ;
Virtanen, S. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (01) :C45-C53
[2]   Low-heating solid-state synthesis and excellent gas-sensing properties of α-Fe2O3 nanoparticles [J].
Cao, Yali ;
Luo, Haiyang ;
Jia, Dianzeng .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 176 :618-624
[3]   Glycine-assisted hydrothermal synthesis of peculiar porous α-Fe2O3 nanospheres with excellent gas-sensing properties [J].
Chen, Hongmin ;
Zhao, Yingqiang ;
Yang, Mingqing ;
He, Junhui ;
Chu, Paul K. ;
Zhang, Jun ;
Wu, Shihua .
ANALYTICA CHIMICA ACTA, 2010, 659 (1-2) :266-273
[4]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[5]   Synthesis, Self-Assembly, and High Performance in Gas Sensing of X-Shaped Iron Oxide Crystals [J].
Dou, Zhi-Feng ;
Cao, Chang-Yan ;
Wang, Qiong ;
Qu, Jin ;
Yu, Yu ;
Song, Wei-Guo .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (10) :5698-5703
[6]   Single-crystal-like hematite colloidal nanocrystal clusters: synthesis and applications in gas sensors, photocatalysis and water treatment [J].
Fang, Xiao-Liang ;
Chen, Cheng ;
Jin, Ming-Shang ;
Kuang, Qin ;
Xie, Zhao-Xiong ;
Xie, Su-Yuan ;
Huang, Rong-Bin ;
Zheng, Lan-Sun .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (34) :6154-6160
[7]   Contact-controlled sensing properties of flowerlike ZnO nanostructures [J].
Feng, P ;
Wan, Q ;
Wang, TH .
APPLIED PHYSICS LETTERS, 2005, 87 (21) :1-3
[8]   Ultrahigh Sensitivity of Au/1D α-Fe2O3 to Acetone and the Sensing Mechanism [J].
Gunawan, Poernomo ;
Mei, Lin ;
Teo, Jaclyn ;
Ma, Jianmin ;
Highfield, James ;
Li, Qiuhong ;
Zhong, Ziyi .
LANGMUIR, 2012, 28 (39) :14090-14099
[9]  
Hwang I. S., SENS ACTUATORS B, V136, P224
[10]   Template-free solvothermal synthesis of hollow hematite spheres and their applications in gas sensors and Li-ion batteries [J].
Kim, Hyo-Joong ;
Choi, Kwon-Il ;
Pan, Anqiang ;
Kim, Il-Doo ;
Kim, Hae-Ryong ;
Kim, Kang-Min ;
Na, Chan Woong ;
Cao, Guozhong ;
Lee, Jong-Heun .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (18) :6549-6555