Determination of pore-size distribution in low-dielectric thin films

被引:186
作者
Gidley, DW [1 ]
Frieze, WE
Dull, TL
Sun, J
Yee, AF
Nguyen, CV
Yoon, DY
机构
[1] Univ Michigan, Dept Phys, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
[3] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA
[4] Seoul Natl Univ, Dept Chem, Seoul 151742, South Korea
关键词
D O I
10.1063/1.126009
中图分类号
O59 [应用物理学];
学科分类号
摘要
Positronium annihilation lifetime spectroscopy is used to determine the pore-size distribution in low-dielectric thin films of mesoporous methylsilsesquioxane. A physical model of positronium trapping and annihilating in isolated pores is presented. The systematic dependence of the deduced pore-size distribution on pore shape/dimensionality and sample temperature is predicted using a simple quantum mechanical calculation of positronium annihilation in a rectangular pore. A comparison with an electron microscope image is presented. (C) 2000 American Institute of Physics. [S0003-6951(00)03810-9].
引用
收藏
页码:1282 / 1284
页数:3
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