A new facile method for the chemoselective reductive transformation of azides to N-(tert-butoxycarbonyl) amines

被引：35
|
作者：
Kotsuki, H
Ohishi, T
Araki, T
机构：
[1] Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 12期
关键词：
D O I：
10.1016/S0040-4039(97)00324-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new chemoselective procedure for the reductive transformation of organic azides to the corresponding N-(tert-butoxycarbonyl) amino derivatives using triethylsilane and di-tert-butyl dicarbonate in the presence of a catalytic amount of 20% Degussa Pd(OH)(2)/C is described. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：2129 / 2132
页数：4
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