Hydrogen bonding and halogen-halogen interactions in 4-halopyridinium halides

被引：87

作者：

Freytag, M

Jones, PG

Ahrens, B

Fischer, AK

机构：

[1] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

[2] Univ Magdeburg, Inst Chem, D-37106 Magdeburg, Germany

来源：

NEW JOURNAL OF CHEMISTRY | 1999年 / 23卷 / 12期

关键词：

D O I：

10.1039/a906356k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solid state structures of the 4-halopyridinium halides 4-XC5H4NH+X- (X = Cl, Br, I) all display chains of the form [... X-C5H4N-H+... X-... X-C5H4N-H+... X-...] involving N-H ... X- hydrogen bonds and X ... X- contacts; the former become longer and the latter shorter (relative to the sum of the van der Waals radii) with increasing size of X.

引用

页码：1137 / 1139

页数：3