Preparation of α-ketophosphonates by oxidation of α-hydroxyphosphonates with chromium-based oxidants

被引：23
作者：
Firouzabadi, H [1 ]
Iranpoor, N [1 ]
Sobhani, S [1 ]
机构：
[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran
来源：
SYNTHETIC COMMUNICATIONS | 2004年 / 34卷 / 08期
关键词：
alpha-ketophosphonates; alpha-hydroxyphosphonates; chlorochromates; dichromates; oxidation;
D O I：
10.1081/SCC-120030697
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Various types of diethyl alpha-hydroxyphosphonates were efficiently converted to diethyl alpha-ketophosphonates by nicotinium dichromate (NDC), nicotinium chlorochromate (NCC), and isonicotinium dichromate (INDC) in high yields.
引用
收藏
页码：1463 / 1471
页数：9
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