Self-Propelled Oil Droplets Consuming "Fuel" Surfactant

被引:217
作者
Toyota, Taro [1 ,3 ]
Maru, Naoto [1 ]
Hanczyc, Martin M. [4 ]
Ikegami, Takashi [2 ]
Sugawara, Tadashi [1 ]
机构
[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Meguro Ku, Tokyo 1538902, Japan
[2] Univ Tokyo, Grad Sch Arts & Sci, Dept Gen Syst Sci, Meguro Ku, Tokyo 1538902, Japan
[3] Chiba Univ, Grad Sch Engn, Dept Appl Chem & Biotechnol, Inage Ku, Chiba 2638522, Japan
[4] Univ So Denmark, Dept Chem & Phys, DK-5230 Odense M, Denmark
关键词
MOTION;
D O I
10.1021/ja806689p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A micrometer-sized oil droplet of 4-octylaniline containing 5 mot % of an amphiphilic catalyst exhibited a self-propelled motion, producing tiny oil droplets, in an aqueous dispersion of an amphiphilic precursor of 4-octylaniline. The tiny droplets on the surface of the self-propelled droplet were conveyed to the posterior surface and released to the aqueous solution. Thus the persistent movement becomes possible in this chemical system, because the processing of chemical energy to mechanical movement proceeds by consuming exogenous fuel, not consuming the oil droplet itself, The mechanism of the unidirectional motion is hypothesized in terms of an asymmetric interfacial tension around the surface of the oil droplet.
引用
收藏
页码:5012 / +
页数:4
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