Nano-structural observation of in situ silica in natural rubber matrix by three dimensional transmission electron microscopy

被引：71

作者：

Ikeda, Y ^{[1
]}

Katoh, A

Shimanuki, J

Kohjiya, S

机构：

[1] Kyoto Inst Technol, Fac Engn & Design, Kyoto 6068585, Japan

[2] NISSAN ARC LTD, Yokosuka, Kanagawa 2370061, Japan

[3] Kyoto Univ, Chem Res Inst, Uji, Kyoto 6110011, Japan

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 12期

关键词：

3D-TEM; electron tomography; in situ silica; nanocomposites; natural rubber;

D O I：

10.1002/marc.200400053

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The three dimansional (3D) nanostructure of particulate in rubber (NR) were observed for the first time by use of 3D transmission electron tomography. The method enabled us to visualize and evaluate structural charachteristics in 3D space, such as the size and the volume of in situ silica generated in the NR matrix by the sol-gel reaction of tetraethoxysilane, at nanometer scale resolution.

引用

页码：1186 / 1190

页数：5

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