Calix[5]arene-Based Heteroditopic Receptor for 2-Phenylethylamine Hydrochloride

被引：44

作者：

Gargiulli, Claudia ^{[1
]}

Gattuso, Giuseppe ^{[1
]}

Liotta, Claudia ^{[1
]}

Notti, Anna ^{[1
]}

Parisi, Melchiorre F. ^{[1
]}

Pisagatti, Ilenia ^{[1
]}

Pappalardo, Sebastiano ^{[2
]}

机构：

[1] Univ Messina, Dipartimento Chim Organ & Biol, I-98166 Messina, Italy

[2] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 11期

关键词：

ION-PAIR EXTRACTION; MOLECULAR RECOGNITION; ANION RECOGNITION; HOST; BINDING; COMPLEXATION; SALTS; SOLVENT; DESIGN; 1,2-DICHLOROETHANE;

D O I：

10.1021/jo802777v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel (1,2-3,5)-calix[5]arene-bis-crown-3 and (1,3)-calix[5]arene-crown-3 derivatives, bearing one or three ureido moieties at the lower rim, respectively, have been synthesized and investigated as heteroditopic receptors for inorganic and organic salts. Tris-ureido-calix[5]arene-crown-3 10, in particular, efficiently binds 2-phenylethylamine hydrochloride (PEA center dot HCl) as a spatially separated ion pair.

引用

页码：4350 / 4353

页数：4

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