Calix[5]arene-Based Heteroditopic Receptor for 2-Phenylethylamine Hydrochloride

被引：42
|
作者：
Gargiulli, Claudia [1 ]
Gattuso, Giuseppe [1 ]
Liotta, Claudia [1 ]
Notti, Anna [1 ]
Parisi, Melchiorre F. [1 ]
Pisagatti, Ilenia [1 ]
Pappalardo, Sebastiano [2 ]
机构：
[1] Univ Messina, Dipartimento Chim Organ & Biol, I-98166 Messina, Italy
[2] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 11期
关键词：
ION-PAIR EXTRACTION; MOLECULAR RECOGNITION; ANION RECOGNITION; HOST; BINDING; COMPLEXATION; SALTS; SOLVENT; DESIGN; 1,2-DICHLOROETHANE;
D O I：
10.1021/jo802777v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Novel (1,2-3,5)-calix[5]arene-bis-crown-3 and (1,3)-calix[5]arene-crown-3 derivatives, bearing one or three ureido moieties at the lower rim, respectively, have been synthesized and investigated as heteroditopic receptors for inorganic and organic salts. Tris-ureido-calix[5]arene-crown-3 10, in particular, efficiently binds 2-phenylethylamine hydrochloride (PEA center dot HCl) as a spatially separated ion pair.
引用
收藏
页码：4350 / 4353
页数：4
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