Asymmetric supported dense lanthanum tungstate membranes

被引：11
作者：
Gil, V. [1 ,2 ]
Gurauskis, J. [1 ,2 ]
Einarsrud, M. -A. [2 ]
机构：
[1] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark
[2] Norwegian Univ Sci & Technol, Dept Mat Sci & Engn, N-7491 Trondheim, Norway
来源：
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2014年 / 34卷 / 15期
关键词：
Proton conductor; Dense ceramic membrane; Lanthanum tungstate; Dip coating; Hydrogen; ELECTRICAL-CONDUCTIVITY; PERMEATION; ACCURACY; OXIDES;
D O I：
10.1016/j.jeurceramsoc.2014.06.019
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
In this work, a colloidal processing route for dense asymmetric La28-xW4+xO54+3x/2 membranes for hydrogen gas separation applications was established. Dip coating process. conditions were optimized to obtain approximate to 20 mu m thick dense layer supported on a porous substrate of the same composition. Surfactants based on electrosteric stabilization were evaluated to obtain stable suspensions in ethanol. The effect of the quantity and type (rice starch and carbon black) of sacrificial pore formers was evaluated for the porous substrates. Based on our results, samples made with 35-45 vol.% carbon black are the best choice to obtain highly porous supports with the optimum characteristics for the fabrication of asymmetric membranes. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3783 / 3790
页数：8
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