Palladium-catalyzed direct asymmetric C-H bond functionalization enabled by the directing group strategy

被引：78
|
作者：
Yang, Ke [1 ]
Song, Mengjie [1 ]
Liu, Hao [2 ]
Ge, Haibo [2 ]
机构：
[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat Sc Technol, Changzhou 213164, Jiangsu, Peoples R China
[2] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA
来源：
CHEMICAL SCIENCE | 2020年 / 11卷 / 47期
关键词：
PLANAR CHIRAL FERROCENES; ENANTIOSELECTIVE SYNTHESIS; C(SP(3))-H BONDS; ATROPOSELECTIVE SYNTHESIS; COUPLING REACTIONS; ARYLATION; ACTIVATION; OLEFINATION; IODINATION; ATROPISOMERS;
D O I：
10.1039/d0sc03052j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the past decade, selective C-C and C-heteroatom bond construction through palladium-catalyzed direct C-H bond functionalization has been extensively studied by employing a variety of directing groups. Within this category, direct asymmetric C(sp(2))-H and C(sp(3))-H activation for the construction of highly enantiomerically enriched skeletons still progressed at a slow pace. This minireview briefly introduces the major advances in the field for palladium-catalyzed direct asymmetric C-H bond functionalization via the directing group strategy.
引用
收藏
页码：12616 / 12632
页数：17
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