Heterobimetallic Lanthanide-Sodium Alkoxides Catalyze the Amidation of Esters

被引：12

作者：

Li, Zhao ^{[1
]}

Wang, Chao ^{[1
]}

Wang, Yaorong ^{[1
]}

Yuan, Dan ^{[1
]}

Yao, Yingming ^{[1
]}

机构：

[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Dushu Lake Campus, Suzhou 215123, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 04期

基金：

中国国家自然科学基金;

关键词：

amidation; amides; amines; esters; heterobimetallic lanthanide complexes; AMIDE BOND FORMATION; SOLVENT-FREE CONDITIONS; TRIMETHYLENE CARBONATE; EPSILON-CAPROLACTONE; AMINO-ALCOHOLS; ASYMMETRIC CATALYSIS; UNACTIVATED ESTERS; CARBOXYLIC ESTERS; ACTIVE CATALYSTS; COMPLEXES;

D O I：

10.1002/ajoc.201800070

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Heterobimetallic lanthanide-sodium alkoxides Ln(2)Na(8)(OCH2CF3)(14)(THF)(6) catalyzed the reaction of esters and amines to produce amides in up to 99% yields. They showed high catalytic activity for a wide scope of substrates under solvent-free conditions. The cooperation of lanthanum and sodium alkoxide is proposed to account for the good activity.

引用

收藏

页码：810 / 814

页数：5

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