Artemisia magellanica. Chemical Composition of the Essential Oil from an Unexplored Endemic Species of Patagonia

被引:6
作者
Gonzalez, Silvia B. [1 ]
Gastaldi, Bruno [1 ]
Catalan, Cesar [2 ]
Di Leo Lira, Paola [3 ,4 ]
Retta, Daiana [3 ,4 ]
van Baren, Catalina M. [3 ,4 ]
Bandoni, Arnaldo L. [3 ,4 ]
机构
[1] Univ Nacl Patagonia San Juan Bosco Sede Esquel, Fac Ciencias Nat & Ciencias Salud, Ruta 259 Km 16,41, RA-9200 Esquel, Chubut, Argentina
[2] Univ Nacl Tucuman, CONICET, Inst Quim Organ, Fac Bioquim Quim & Farm,INQUINOA, Ayacucho 471, RA-4000 San Miguel De Tucuman, Argentina
[3] Univ Buenos Aires, Fac Farm & Bioquim, Catedra Farmacognosia, Junin 956,2 Piso, RA-1113 Buenos Aires, DF, Argentina
[4] Univ Buenos Aires, CONICET, Inst Quim & Metab Farmaco IQUIMEFA, Junin 956,2 Piso, RA-1113 Buenos Aires, DF, Argentina
关键词
Artemisia magellanica; Artemisia biennis; Patagonia; gamma-costol; native aromatic plants; ENANTIOMERIC DISTRIBUTION; ANTIOXIDANT ACTIVITIES; GENUS ARTEMISIA; L; ASTERACEAE; GROWING WILD; ACHILLEA; LEAVES; SIEVERSIANA; BIOLOGY; WILLD;
D O I
10.1002/cbdv.201900125
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The essential oil composition of the aerial parts of Artemisia magellanica Sch. Bip. (Asteraceae), native to Patagonia, was analyzed by GC-FID-MS. This is the first report on the essential oil composition of A. magellanica. A total of 113 components were identified accounting for 95.6-95.7 % of the oil. The essential oil was characterized by a high percentage of gamma-costol (21.0-43.5 %), selina-4,11-diene, (Z)-beta-ocimene, (E)-beta-farnesene, (Z)-en-yn-dicycloether and 23 different esters (28.7 %). In turn, Artemisia biennis, a species native to North America, which is considered by some authors to be conspecific with A. magellanica, yielded an essential oil that was rich in (Z)-beta-ocimene (34.7 %), (E)-beta-farnesene (40.0 %) and the acetylenes (Z)- and (E)-en-yn-dicycloethers (11.0 %). Thus, as A. biennis lacks the three main components present in A. magellanica, namely gamma-costol, 2-methylbutyl 2-methylbutyrate and selina-4,11-diene, these compounds could be considered as potential chemical markers for A. magellanica since they are absent or only found as minor constituents in other members of the genus. The data presented herein is also useful for genus taxonomy.
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页数:9
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