Influence of cerium content and heat treatment on Ce:YAG@glass wool nanostructures

被引:4
作者
Armetta, Francesco [1 ,2 ]
Defilippi, Chiara [3 ]
Giordano, Cristina [3 ]
Caponetti, Eugenio [1 ,2 ]
Marciniak, Lukasz [4 ]
Hreniak, Dariusz [4 ]
Saladino, Maria Luisa [1 ,2 ]
机构
[1] Univ Palermo, Diparimento Sci & Tecnol Biol, Chim & Famaceut STEBICEF, Viale Sci Pad 17, I-90128 Palermo, Italy
[2] Univ Palermo, INSTM UdR Palermo, Viale Sci Pad 17, I-90128 Palermo, Italy
[3] Queen Mary Univ London, Sch Biol & Chem Sci, Mile End Rd, London E1 4NS, England
[4] Polish Acad Sci, Inst Low Temp & Struct Res, Ul Okolna 2, Wroclaw, Poland
关键词
Urea glass route; YAG; Glass wool; Layer of nanoparticles; Synthetic route; ENHANCED LIGHT EXTRACTION; OPTICAL-PROPERTIES; LOCAL-STRUCTURE; SINGLE; YAGCE; CE; MICROSTRUCTURE; NANOPARTICLES; LUMINESCENCE; Y3AL5O12CE3+;
D O I
10.1007/s11051-019-4589-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The paper reports the influence of cerium content and heat treatment on composition, structural features and optical properties of nanostructures constituted by a layer of Ce:YAG nanoparticles on glass wool (Ce:YAG@GW). The Ce:YAG@GW nanostructures were obtained embedding the glass wool (GW) in a gel-like precursor and calcining at 800 and 900 degrees C. Gel-like precursor of urea glass route (UGR) method has been used to prepare both nanostructures and Ce:YAG nanoparticles prepared as references. Structural properties were investigated by using X-ray diffraction (XRD) and infrared spectroscopy (IR). Results showed that the composition of the final products strongly depends both on the cerium content and temperature. Optical properties of best materials have been investigated in order to verify their suitability for lighting applications. Obtained results show relatively high quantum efficiency for Ce:YAG@GW treated at 800 degrees C comparing with the Ce:YAG nanoparticles obtained at the same temperature confirming the improved luminescence properties of the nanoparticles when they are applied on GW surface.
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页数:9
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