Syntheses, electrochemistry and electrodeposition of ruthenium(II) complexes of 4,4'-bis(4-anilinovinyl)-2,2'-bipyridine

被引：3

作者：

Storrier, GD ^{[1
]}

Colbran, SB ^{[1
]}

机构：

[1] UNIV NEW S WALES,SCH CHEM,SYDNEY,NSW 2052,AUSTRALIA

来源：

POLYHEDRON | 1997年 / 16卷 / 16期

关键词：

anilinovinyl-bipyridine; ruthenium(II); electropolymerization;

D O I：

10.1016/S0277-5387(97)00049-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new disubstituted bipyridine ligand, 4,4'-bis(4-anilinovinyl)-2,2'-bipyridine (L-2), and its homoleptic and heteroleptic ruthenium(II) complexes [RuL32](2+) and [RuL2(bpy)(2)](2+) are described. Both complexes undergo electrochemical polymerization in acetonitrile. [RuL2(bpy)(2)](2+) produced a conducting but non-robust polymer film, while [RuL32](2+) produced an insulating him. (C) 1997 Elsevier Science Ltd.

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页码：2705 / 2710

页数：6

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