Odrourless Strategy for Deep Eutectic Solvent-Mediated Ring Opening of Epoxides with In Situ Generated S-Alkylisothiouronium Salts

被引：17
作者：
Azizi, Najmedin [1 ]
Yadollahy, Zahra [1 ]
Rahimzadeh-oskooee, Amin [1 ]
机构：
[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
来源：
SYNLETT | 2014年 / 25卷 / 08期
关键词：
deep eutectic solvent; epoxide; odourless thiol chemistry; ONE-POT SYNTHESIS; POLYETHYLENE-GLYCOL; EFFICIENT SYNTHESIS; MESO-EPOXIDES; THIIRANES; OXIRANES; THIOLYSIS; WATER; CONVERSION; CATALYST;
D O I：
10.1055/s-0033-1341050
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A general, straightforward and odourless ring-opening reaction allows the preparation of beta-hydroxy sulfides from in situ generated S-alkylisothiouronium salts in urea-choline chloride-based deep eutectic solvent (DES). In addition, reaction of epoxides with thiourea in DES yields the corresponding thiiranes.
引用
收藏
页码：1085 / 1088
页数：4
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