Odrourless Strategy for Deep Eutectic Solvent-Mediated Ring Opening of Epoxides with In Situ Generated S-Alkylisothiouronium Salts

被引：18

作者：

Azizi, Najmedin ^{[1
]}

Yadollahy, Zahra ^{[1
]}

Rahimzadeh-oskooee, Amin ^{[1
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran

来源：

SYNLETT | 2014年 / 25卷 / 08期

关键词：

deep eutectic solvent; epoxide; odourless thiol chemistry; ONE-POT SYNTHESIS; POLYETHYLENE-GLYCOL; EFFICIENT SYNTHESIS; MESO-EPOXIDES; THIIRANES; OXIRANES; THIOLYSIS; WATER; CONVERSION; CATALYST;

D O I：

10.1055/s-0033-1341050

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general, straightforward and odourless ring-opening reaction allows the preparation of beta-hydroxy sulfides from in situ generated S-alkylisothiouronium salts in urea-choline chloride-based deep eutectic solvent (DES). In addition, reaction of epoxides with thiourea in DES yields the corresponding thiiranes.

引用

收藏

页码：1085 / 1088

页数：4

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