Induced halogenation of alkyl cyclohexenyl ketones involving metal halides, hydrohalogenic acids, and hydrogen peroxide

被引:1
作者
Sadygov, O. A. [1 ]
Alimardanov, Kh. M. [1 ]
机构
[1] Natl Acad Sci Azerbaidzhan, Mamedaliev Inst Petrochem Engn, AZ-1025 Baku, Azerbaijan
关键词
Ketone; NaOCl; Enone; Ethanone; Hydroxycyclohexyl;
D O I
10.1134/S107042800902002X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The induced halogenation and hydroxyhalogenation of alkyl cyclohexenyl ketones in a system [MHlg + HHlg or HHlg]-H(2)O(2) or in NaOCl was performed and optimum reaction conditions were established. Under mild conditions the electrophilic addition of the halogen or the acid occurred at the multiple bond of the ring with the formation of the corresponding dihalo or hydroxyhalo derivatives of cycloaliphatic ketones. From the compounds obtained epoxy- and dioxyketones of aliphatic series were prepared. Chloro(bromo)hydrins of ketones from the alkylcyclohexane series and oxiranes based thereon are reactive compounds and can be employed as synthons in the organic synthesis.
引用
收藏
页码:166 / 172
页数:7
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