Synthesis and Characterization of an Imidazole-Containing Pyrene π-System

被引:12
作者
Liu, Yulong [1 ]
Gao, Zhao [1 ]
Wang, Zhiming [1 ]
Feng, Cunfang [1 ]
Shen, Fangzhong [1 ]
Lu, Ping [1 ]
Ma, Yuguang [1 ]
机构
[1] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
Aggregation; Arenes; Conjugation; Nitrogen heterocycles; Optoelectronics; STABILITY;
D O I
10.1002/ejoc.201301285
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A one-pot reaction is used in the creation of a novel skeleton by using pyrene and the five-membered imidazole ring as the key units. The two new compounds show high thermal stability. Deep-blue emissions are observed in solution for both compounds, which have a strong tendency to aggregate into thin films and a tendency to crystallize as powders. These properties are indicative of their potential application in organic electronic devices.
引用
收藏
页码:7267 / 7271
页数:5
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