Renewable epoxidized cardanol-based acrylate as a reactive diluent for UV-curable resins

被引：36
作者：
Hu, Yun [1 ,2 ,3 ]
Shang, Qianqian [1 ,2 ,3 ]
Wang, Cuina [4 ]
Feng, Guodong [1 ,2 ,3 ]
Liu, Chengguo [1 ,2 ,3 ]
Xu, Feng [5 ]
Zhou, Yonghong [1 ,2 ,3 ]
机构：
[1] Chinese Acad Forestry, Inst Chem Ind Forest Prod, Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China
[2] State Forestry Adm, Natl Engn Lab Biomass Chem Utilizat, Nanjing 210042, Jiangsu, Peoples R China
[3] State Forestry Adm, Key Lab Forest Chem Engn, Nanjing 210042, Jiangsu, Peoples R China
[4] Nanjing Forestry Univ, Coll Sci, Nanjing 210037, Jiangsu, Peoples R China
[5] Beijing Forestry Univ, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 2018年 / 29卷 / 06期
关键词：
biobased; cardanol; diluent; UV-curable resins; CROSS-LINK AGENT; SOYBEAN-OIL; CASTOR-OIL; MULTIFUNCTIONAL MONOMERS; POLYURETHANE ACRYLATE; EPOXY-RESIN; THIOL-ENE; COATINGS; LIGNIN; ROSIN;
D O I：
10.1002/pat.4294
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel kind of biobased monomer, epoxidized cardanol-based acrylate (ECA), was successfully synthesized from cardanol via acrylation and epoxidization. The chemical structure was confirmed by Fourier transform infrared spectroscopy and proton nuclear magnetic resonance. Then, the ECA was employed to produce UV-curable films and coatings copolymerized with castor oil-based polyurethane acrylate. Compared to coatings from petroleum-based diluent hydroxyethyl acrylate-based castor oil-based polyurethane acrylate resins, ECA-based biomaterials exhibited a little inferior dilution ability but overcome the drawback of high volumetric shrinkage with a special lower value. Moreover, ultimate properties of the UV-cured biomaterials such as thermal, mechanical, coating, swelling, and hydrophobic properties were investigated. The UV-curing behavior was investigated using real-time IR, and the overall double bond conversion was more than 90%. This biobased UV-curable cardanol-based diluent shows a promise in green + green materials technologies.
引用
收藏
页码：1852 / 1860
页数：9
相关论文
共 41 条
[1]  
Acosta Ortiz R, 2015, J POLYM RES, V22, P359
[2]   Vegetable oil based eco-friendly coating materials: A review article [J].
Alam, Manawwer ;
Akra, Deewan ;
Sharmin, Eram ;
Zafar, Fahmina ;
Ahmad, Sharif .
ARABIAN JOURNAL OF CHEMISTRY, 2014, 7 (04) :469-479
[3]  
Aouf C, 2013, SYNTHESIS NOVEL BIO, V6, P1195
[4]   Synthesis and characterization of cardanol based reactive polyamide for epoxy coating application [J].
Balgude, Dinesh ;
Sabnis, Anagha ;
Ghosh, Swapan K. .
PROGRESS IN ORGANIC COATINGS, 2017, 104 :250-262
[5]   Synthesis of a cardanol-based phosphorus-containing polyurethane prepolymer and its application in phenolic foams [J].
Bo, Caiying ;
Wei, Shikang ;
Hu, Lihong ;
Jia, Puyou ;
Liang, Bingchuang ;
Zhou, Jing ;
Zhou, Yonghong .
RSC ADVANCES, 2016, 6 (67) :62999-63005
[6]   Allylamino diphenylphosphine oxide and poss containing flame retardant photocured hybrid coatings [J].
Cakmakci, Emrah .
PROGRESS IN ORGANIC COATINGS, 2017, 105 :37-47
[7]   Synthesis and characterization of UV-curable castor oil-based polyfunctional polyurethane acrylate via photo-click chemistry and isocyanate polyurethane reaction [J].
Chen, Guangxue ;
Guan, Xiaoyuan ;
Xu, Ruixin ;
Tian, Junfei ;
He, Minghui ;
Shen, Wei ;
Yang, Jianwen .
PROGRESS IN ORGANIC COATINGS, 2016, 93 :11-16
[8]   Synthesis and Application of Polyepoxide Cardanol Glycidyl Ether as Biobased Polyepoxide Reactive Diluent for Epoxy Resin [J].
Chen, Jie ;
Nie, Xiaoan ;
Liu, Zengshe ;
Mi, Zhen ;
Zhou, Yonghong .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (06) :1164-1171
[9]   Study of epoxidized-cardanol containing cationic UV curable materials [J].
Chen, Zhigang ;
Chisholm, Bret J. ;
Webster, Dean C. ;
Zhang, Ying ;
Patel, Sandeep .
PROGRESS IN ORGANIC COATINGS, 2009, 65 (02) :246-250
[10]   Soybean oil-based UV-curable coatings strengthened by crosslink agent derived from itaconic acid together with 2-hydroxyethyl methacrylate phosphate [J].
Dai, Jinyue ;
Liu, Xiaoqing ;
Ma, Songqi ;
Wang, Jinggang ;
Shen, Xiaobin ;
You, Shusen ;
Zhu, Jin .
PROGRESS IN ORGANIC COATINGS, 2016, 97 :210-215
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