Thermodynamic analysis of the change of solid solubility in a binary system processed by mechanical alloying

被引:24
|
作者
Aguilar, C. [1 ]
Martinez, V. [2 ]
Navea, L. [3 ]
Pavez, O. [3 ]
Santander, M. [3 ]
机构
[1] Univ Austral Chile, Inst Mat & Proc Termomecan, Fac Ciencias Ingn, Valdivia, Chile
[2] Met Solut SL, TEKMETALL, Donostia Gipuzkoa 20018, Spain
[3] Univ Atacama, Dept Met, Fac Ingn, Copiapo, Chile
关键词
Thermodynamic modeling; Mechanical alloying; Metals and alloys; Nanostructured materials; DIFFRACTION PROFILE ANALYSIS; GRAIN-SIZE CHANGES; PHASE-TRANSFORMATIONS; NANOCRYSTALLINE FE; CU POWDERS; ATTRITION; MICROSTRUCTURE; AMORPHIZATION; NICKEL;
D O I
10.1016/j.jallcom.2008.03.083
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using a non-equilibrium process, it is possible to extend the solid solubility range in metallic systems. Therefore, the main objective of this work was to apply a thermodynamic model to predict the change in the solubility limit of systems with positive enthalpy mixing (Cu-Cr and Fe-Cu) processed by mechanical alloying. It was found that increasing the density of crystalline defects alters the solubility limit in these binary systems. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:336 / 340
页数:5
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