Recent advances in asymmetric Strecker reactions

被引：56

作者：

Cai, Xiao-Hua ^{[1
]}

Xie, Bing ^{[1
]}

机构：

[1] Guizhou Minzin Univ, Coll Chem & Environm Sci, Guiyang 550025, Peoples R China

来源：

ARKIVOC | 2014年

基金：

中国国家自然科学基金;

关键词：

Asymmetric Strecker reaction; alpha-amino acids; enantioselective; chiral metal complex catalysts; chiral organocatalysts; AMINO-ACID SYNTHESIS; HYDROGEN-CYANIDE; STEREOSELECTIVE-SYNTHESIS; EFFICIENT SYNTHESIS; ONE-POT; IMINES; CYANATION; KETIMINES; ALDIMINES; CATALYSIS;

D O I：

10.3998/ark.5550190.p008.487

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Strecker reaction is one of the most attractive methods for the synthesis of beta-amino acids and other bioactive compounds including natural products. The asymmetric Strecker reaction represents a simple and efficient method for the synthesis of optically pure beta-amino acid derivatives, nucleic acids, various nitrogen and sulfur containing heterocycles and pharmaceuticals. Over the past several decades, considerable effort has been devoted towards the development of asymmetric Strecker reactions. This review provides an overview of recent asymmetric Strecker reactions, from diastereoselective reactions and catalytic enantioselective reactions including chiral catalytic metal systems and chiral organocatalytic systems.

引用

页码：205 / 248

页数：44

共 93 条

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