Organophotoredox/Copper Hybrid Catalysis for Regioselective Allylic Aminodecarboxylation of β,γ-Unsaturated Carboxylic Acids

被引：5

作者：

Manick, Anne-Doriane ^{[1
]}

Tanaka, Hirotaka ^{[1
]}

Oisaki, Kounosuke ^{[1
]}

Kanai, Motomu ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan

来源：

SYNTHESIS-STUTTGART | 2018年 / 50卷 / 15期

关键词：

photoredox catalysis; copper; decarboxylation; beta; gamma-unsaturated carboxylic acids; allylic hydrazides; dual catalysis; ALPHA-KETO ACIDS; ORGANIC PHOTOREDOX CATALYSIS; C-BOND FORMATION; ASYMMETRIC-SYNTHESIS; DECARBOXYLATIVE AMIDATION; MERGING PHOTOREDOX; COUPLING REACTIONS; DERIVATIVES; ALCOHOLS; AMINES;

D O I：

10.1055/s-0036-1591983

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new cooperative organophotoredox/copper catalysis allowing for the conversion of ,-unsaturated carboxylic acids into allylic hydrazides via radical regioselective allylic decarboxylative amination is reported. The coexistence of the copper catalyst is essential for the high yield and regioselectivity.

引用

页码：2936 / 2947

页数：12

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