Acidic sites in beta zeolites in dependence of the preparation methods

被引:24
作者
Dimitrova, R
Gunduz, G
Dimitrov, L
Tsoncheva, T
Yialmaz, S
Urquieta-Gonzalez, EA
机构
[1] Bulgarian Acad Sci, Inst Organ Chem, BU-1113 Sofia, Bulgaria
[2] Ege Univ, Dept Chem Engn, Izmir, Turkey
[3] Bulgarian Acad Sci, Inst Catalysis, BU-1113 Sofia, Bulgaria
[4] Izmir Inst Technol, Dept Chem Engn, Izmir, Turkey
[5] Univ Fed Sao Carlos, Ctr Ciencias Exatas & Tecnol, BR-13560 Sao Carlos, Brazil
关键词
acid beta zeolites; mesostructured beta seeds; methanol conversion;
D O I
10.1016/j.molcata.2003.12.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Beta zeolites synthesized by different methods are compared in their structure peculiarities and acidic properties by nitrogen physisorption, IR-KBr. pyridine sorption-desorption and thermoprogrammed desorption of ammonia. It is found that mesopores could be obtained in beta zeolites with the change of the activation procedure. Methanol conversion to dimethyl ether and hydrocarbons is used as a test reaction for understanding of the acid center function. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:265 / 268
页数:4
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