Synthesis, characterization and photoluminescence properties of monoporphyrinate lanthanide complexes

被引：26
作者：
He, HS
Wong, WK
Li, KF
Cheah, KW
机构：
[1] Huaqiao Univ, Dept Appl Chem, Quanzhou 362011, Peoples R China
[2] Hong Kong Baptist Univ, Dept Chem, Kowloon, Hong Kong, Peoples R China
[3] Hong Kong Baptist Univ, Dept Phys, Kowloon, Hong Kong, Peoples R China
来源：
SYNTHETIC METALS | 2004年 / 143卷 / 01期
关键词：
lanthanides; luminescence; sensitizers; porphyrinate complexes;
D O I：
10.1016/j.synthmet.2003.10.011
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Eight monoporphyrinate lanthanide complexes of the general formula [Ln(Por)(H2O)(3)]Cl (Ln = Yb3+ and Er3+, Por = tetraphenyl-porphyrin dianion (TPP2-)and its para-substituted derivatives) were prepared and characterized by elemental analyses, MS, IR and UV-Vis spectra. Photoluminescence Studies showed that porphyrinate dianion absorbed the visible light, transferred the energy to lanthanide ions and enabled the later emitting in the near-infrared region. The effects of substituent and solvent on the photoluminescence efficiency were also discussed. (C) 2003 Elsevier B.V. All rights reserved.
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页码：81 / 87
页数：7
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