Synthesis, structure, and properties of dinuclear copper (II) complex with a (H2O)12 cluster

被引：19

作者：

Hu, Feilong ^{[1
]}

Yin, Xianhong ^{[1
]}

Mi, Yan ^{[1
]}

Zhang, Jinlei ^{[1
]}

Zhuang, Yue ^{[1
]}

Dai, Xianzhen ^{[1
]}

机构：

[1] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning 53006, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Dinuclear copper (II); Water hexamers; Electrochemical; Photoluminescence; CRYSTAL-STRUCTURES; WATER CLUSTERS; FRAMEWORK; LIGANDS; ANIONS; CHAIN; CUBE;

D O I：

10.1016/j.inoche.2009.05.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel pyrazole complex, namely [Cu-2(4,4'-bpy)(2)(2,2'-bpy)(L)(2)]center dot 6H(2)O has been synthesized under mild condition (4,4'-bpy = 4,4'-bipyridine, 2,2'-bpy = 2,2'-bipyridine). We report the structural evidence in the solid state of discrete water hexamers chair-like conformation. These units were found to act as supramolecular glue in the aggregation of dinuclear copper (II) complex to give a three dimensional network through hydrogen-bonding. The preliminary investigation on the electrochemical property and fluorescence property of the complex are presented. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.

引用

页码：628 / 631

页数：4

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