Bromination of a Stable 1,2-Bis(ferrocenyl) dibismuthene: Synthesis of a 1,2-Dibromodibismuthane Derivative

被引：6

作者：

Sasamori, Takahiro ^{[1
]}

Sakagami, Michiyasu ^{[1
]}

Tokitoh, Norihiro ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

来源：

HETEROATOM CHEMISTRY | 2014年 / 25卷 / 05期

关键词：

DOUBLY BONDED SYSTEMS; ORGANOMETALLIC COMPOUNDS; ELEMENTS; BI; DIPNICTENES; REACTIVITY; COMPOUND; CRYSTAL; SB;

D O I：

10.1002/hc.21154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bromination reaction of the stable bis(ferrocenyl)dibismuthene, Fc*Bi=BiFc* (1, Fc* = 2,5-bis(3,5-di-t-butylphenyl)ferrocenyl), with 0.5 equiv of BiBr3 resulted in the formation of the first stable 1,2-dibromodibismuthane derivative, Fc*(Br)Bi-Bi(Br)Fc* (3). The structure of 3 was revealed by X-ray crystallographic analysis, showing its unique structure with the bromine atom intramolecularly coordinating to the bismuth atom.

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页码：306 / 312

页数：7

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