Self-assembly of heterosupermolecules

被引:30
作者
Cusack, L [1 ]
Rao, SN [1 ]
Wenger, J [1 ]
Fitzmaurice, D [1 ]
机构
[1] NATL UNIV IRELAND UNIV COLL DUBLIN,DEPT CHEM,DUBLIN 4,IRELAND
关键词
D O I
10.1021/cm9604470
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2 nanocrystallites are prepared by hydrolysis of titanium tetraisopropoxide in the presence of N,N'-2,6-pyridinediylbis[undecamide]. The latter stabilizes the resulting semiconductor sol and provides sites at the surface of a nanocrystallite for selective binding of a uracil derivative by complementary hydrogen bonding. Addition of 6-(N-tridecylundecamido)methyluracil results in self-assembly of a heterosupermolecule subsequently characterized by H-1 NMR and FT-IR spectroscopies.
引用
收藏
页码:624 / 631
页数:8
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