New ferrocene-containing structures: Poly(silyl ester)s

被引：22
作者：
Cazacu, Maria
Munteanu, Grigore
Racles, Carmen
Vlad, Angelica
Marcu, Mihai
机构：
[1] Petru Poni Inst Macromol Chem, Iasi 700487, Romania
[2] Moldavian Acad Sci, Inst Chem, MD-2028 Chishinew, Moldova
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 17期
关键词：
ferrocene-containing polymers; inorganic polymers; poly(silyl ester)s; siloxane-containing polymers; redox active polymers; RING-OPENING POLYMERIZATION; HIGH-MOLECULAR-WEIGHT; ORGANOMETALLIC POLYMERS; SILOXANE POLYMERS; BLOCK-COPOLYMERS; DERIVATIVES; POLYCONDENSATION; CONDENSATION; MONOMERS; ROUTE;
D O I：
10.1016/j.jorganchem.2006.05.026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new polymeric structures containing ferrocene units along the chains, namely poly(silyl ester)s, have been synthesized and characterized: a geminal poly(silyl ester) (g-PSE) and one having a disiloxane spacer between the silyl ester groups (s-PSE). The condensation polymerization of AA/BB monomer systems in solution was used in both cases as preparation method involving a silicon-containing diol, (diphenyisilane diol or 1,3-bis(hydroxy)-tetramethyldisiloxane), and 1,1'-di(chlorocarbonyl)ferrocene. The polymers were investigated by differential pulse voltammetry in order to evaluate the redox behavior. Due to the presence of the silyl ester groups in the chain, these polymers are hydrolytically degradable. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：3700 / 3707
页数：8
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