The catalytic acylation of alcohols with acetic acid by using Lewis acid character pillared clays

被引：18

作者：

Akçay, M ^{[1
]}

机构：

[1] Dicle Univ, Fac Sci & Art, Dept Chem, TR-21280 Diyarbakir, Turkey

来源：

APPLIED CATALYSIS A-GENERAL | 2004年 / 269卷 / 1-2期

关键词：

Lewis acids; catalysts; clays; acylation;

D O I：

10.1016/j.apcata.2004.04.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple and efficient method was developed for acylation of alcohols, using pillared clay catalyst such as {Fe-pillc, Cr-pillc, Cr-(Fe-pillc) and Fe-(Cr-pillc)} and a carboxylic acid as acylating agent. The pillared clay catalysts were calcined after incorporation of metal polycation ions with exchangeable cations and water. In the present study, the aliphatic alcohol (n-hexanol) and the aromatic alcohol (benzylalcohol) were acylated by using acetic acid and pillared clays. In these reactions it has been found that pillared clays have excellent catalytic activity. In direct acylation with acetic acid of alcohols (n-hexanol and benzylalcohol), pillared clays showed excellent catalytic activity. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：157 / 160

页数：4

共 25 条

[1]

Adams JM, 1987, APPL CLAY SCI, V2, DOI DOI 10.1016/0169-1317(87)90039-1

[2] FTIR study of the adsorption of ammonia and pyridine on V2O5/MgO catalysts [J].

Akçay, M ;

Yurdakoç, M ;

Tonbul, Y ;

Yurdakoç, K ;

Hönicke, D .

SPECTROSCOPY LETTERS, 1998, 31 (08) :1719-1732

[3]

Baker RH., 1955, ORG SYNTH, P141

[4]

Ballantine J. A., 1986, NATO ASI SER C, V165, P197

[5]

Ballantine J. A., 1992, SOLID SUPPORTS CATAL, P100

[6]

BALLANTINE JA, 1987, CHEM ABSTR, V106, P4297

[7] Per-O-acetylation of sugars catalysed by montmorillonite K-10 [J].

Bhaskar, PM ;

Loganathan, D .

TETRAHEDRON LETTERS, 1998, 39 (15) :2215-2218

[8] Industrial applications of acid-treated clays as catalysts [J].

Chitnis, SR ;

Sharma, MM .

REACTIVE & FUNCTIONAL POLYMERS, 1997, 32 (01) :93-115

[9]

Cope A.C., 1963, ORG SYNTH, V4, P304

[10] Ionic liquid as a green catalytic reaction medium for esterifications [J].

Deng, YQ ;

Shi, F ;

Beng, JJ ;

Qiao, K .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 165 (1-2) :33-36

← 1 2 3 →