The Electron-Transfer Rate Processes In Biological Systems

被引：0
|
作者：
Zhu, Hanjun [1 ]
Bai, Tong-Chun [2 ]
Wei, Dongqing [3 ]
机构：
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11796 USA
[2] Suzhou Univ, Dept Chem, Suzhou, Peoples R China
[3] Shanghai Jiao Tong Univ, Dept Bioinformix, Shanghai, Peoples R China
来源：
THEORY AND APPLICATIONS OF COMPUTATIONAL CHEMISTRY - 2008 | 2009年 / 1102卷
关键词：
Biological Electron Transfer Rate; CHARGE-TRANSFER; POLAR-SOLVENTS; FREE-ENERGY; DYNAMICS; QUANTUM;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction coordinates for the electron transfer (ET) reactions are discussed. The channel-based reaction-diffusion equations are solved analytically for two biological electron transfer models, which allow us build an ET rate constant which modifies the Marcus-Jortner formula by adding a dynamic correction factor. The dynamic correction factor can reduce the ET rate by orders of magnitude. The theory has been compared with experiment with fairly good result.
引用
收藏
页码：244 / +
页数：2
相关论文
共 50 条
  • [31] THERMAL AND OPTICAL ELECTRON-TRANSFER PROBABILITIES IN BIOLOGICAL-SYSTEMS
    HUSH, NS
    INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1983, 79 (1-6): : 55 - 55
  • [32] Intermediates produced in the electron-transfer processes of phenothiazine/semiconductor systems
    Jian, HH
    Xiang, JF
    Sun, K
    Sun, J
    Chen, CP
    Zhou, BM
    Liu, Y
    Xu, GZ
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 229 (01) : 212 - 216
  • [33] DYNAMICS OF INTERFACIAL ELECTRON-TRANSFER PROCESSES IN COLLOIDAL SEMICONDUCTOR SYSTEMS
    DUONGHONG, D
    RAMSDEN, J
    GRATZEL, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (11) : 2977 - 2985
  • [34] Electron-Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals
    Awaga, Kunio
    Nomura, Kenji
    Kishida, Hideo
    Fujita, Wataru
    Yoshikawa, Hirofumi
    Matsushita, Michio M.
    Hu, Laigui
    Shuku, Yoshiaki
    Suizu, Rie
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2014, 87 (02) : 234 - 249
  • [35] ELECTRON-TRANSFER PROCESSES - REACTION OF ELECTRON-RICH SYSTEMS WITH ACTIVATED AZOMETHINES
    COLONNA, M
    POLONI, M
    GAZZETTA CHIMICA ITALIANA, 1985, 115 (03): : 187 - 189
  • [36] ELECTRON-TRANSFER PROCESSES - REACTIONS OF ELECTRON-RICH SYSTEMS WITH ACTIVATED AZOMETHINES
    COLONNA, M
    CHIMICA & L INDUSTRIA, 1984, 66 (11): : 710 - 717
  • [37] CONTROL OF SPECIFICITY IN BIOLOGICAL ELECTRON-TRANSFER
    CUSANOVICH, MA
    MEYER, TE
    TOLLIN, G
    BIOPHYSICAL JOURNAL, 1986, 49 (02) : A26 - A26
  • [38] THERMODYNAMICS OF ELECTRON-TRANSFER AND ITS COUPLING TO VECTORIAL PROCESSES IN BIOLOGICAL-MEMBRANES
    ARATA, H
    NISHIMURA, M
    BIOPHYSICAL JOURNAL, 1980, 32 (02) : 791 - 806
  • [39] MODELS FOR BIMOLECULAR ELECTRON-TRANSFER PROCESSES
    NEWTON, MD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 39 - PHYS
  • [40] Catalytic control of electron-transfer processes
    Fukuzumi, S
    PURE AND APPLIED CHEMISTRY, 2003, 75 (05) : 577 - 587
12345